ASTM C114-11b

1.1 These test methods cover the chemical analyses of hydraulic cements. Any test methods of demonstrated acceptable precision and bias may be used for analysis of hydraulic cements, including analyses for referee and certification purposes, as explained in Section 4. Specific chemical test methods are provided for ease of reference for those desiring to use them. They are grouped as Reference Test Methods and Alternative Test Methods. The reference test methods are long accepted classical chemical test methods which provide a reasonably well-integrated basic scheme of analysis for hydraulic cements. The alternative test methods generally provide individual determination of specific analytes and may be used alone or as alternates and determinations within the basic scheme at the option of the analyst and as indicated in the individual method.

1.2 Contents:

Section Subject

2 Referenced Documents

4 Description of Referee Analyses

4.1 Referee Analyses

5 Qualification for Different Analyses

5.1 Certified Reference Materials

5.2 Requirements for Qualification Testing

5.3 Alternative Analyses

5.4 Performance Requirements for Rapid Test Methods

6 General

6.1 Interferences and Limitations

6.2 Apparatus and Materials

6.3 Reagents

6.4 Sample Preparation

6.5 General Procedures

6.6 Recommended Order for Reporting Analyses Reference Test Methods

7 Insoluble Residue

8 Silicon Dioxide

8.2 Cements with Insoluble Residue Less Than 1 %

8.3 Cements with Insoluble Residue Greater Than 1 %

9 Ammonium Hydroxide Group

10 Ferric Oxide

11 Phosphorus Pentoxide

12 Titanium Dioxide

13 Zinc Oxide

14 Aluminum Oxide

15 Calcium Oxide

16 Magnesium Oxide

17 Sulfur

17.1 Sulfur Trioxide

17.2 Sulfide

18 Loss On Ignition

18.1 Portland Cement

18.2 Portland Blast-Furnace Slag Cement and Slag Cement

19 Sodium and Potassium Oxides

19.1 Total Alkalis

19.2 Water-Soluble Alkalis

20 Manganic Oxide

21 Chloride

22 Chloroform-Soluble Organic Substances Alternative Test Methods

23 Calcium Oxide

24 Carbon Dioxide

25 Magnesium Oxide

26 Loss on Ignition

26.1 Portland Blast-Furnace Slag Cement and Slag Cement

27 Titanium Dioxide

28 Phosphorus Pentoxide

29 Manganic Oxide

30 Free Calcium Oxide

Appendices Title

Appendix X1 Example of Determination of Equivalence Point for the Chloride Determination

Appendix X2 CO2 Determinations in Hydraulic Cements

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. See 8.3.2.1 and 16.4.1 for specific caution statements.